|
|
N,N-dihydroxy-L-phenylalanine + H+ <=> (E)-phenylacetaldoxime + CO2 + H2O
|
1.14.14.40
phenylalanine N-monooxygenase
|
–
|
MK
|
|
BRENDA:
BR49592
KEGG:
R09581
MetaCyc:
RXN-12068
|
|
|
|
(E)-phenylacetaldoxime <=> (Z)-phenylacetaldoxime
|
1.14.14.44
phenylacetaldehyde oxime monooxygenase
|
–
|
MK
|
|
BRENDA:
BR52033
KEGG:
R10041
MetaCyc:
RXN-12065
|
|
|
|
L-phenylalanine + 2 reduced_flavodoxin + 2 O2 <=> (E)-phenylacetaldoxime + 2 flavin + CO2 + 3 H2O
|
1.14.14.40
phenylalanine N-monooxygenase
|
–
|
K
|
|
BRENDA:
BR49589
KEGG:
R09578
|
|
|
|
(E)-phenylacetaldoxime + reduced_flavodoxin + O2 <=> (R)-mandelonitrile + flavin + 2 H2O
|
1.14.14.44
phenylacetaldehyde oxime monooxygenase
|
–
|
|
|
BRENDA:
BR52032
KEGG:
R11732
|
|
|
|
(E)-phenylacetaldoxime + reduced_flavodoxin + glutathione + O2 <=> S-[(Z)-N-hydroxy(phenyl)acetimidoyl]-L-glutathione + flavin + 2 H2O
|
1.14.14.45
aromatic aldoxime N-monooxygenase
|
–
|
|
|
BRENDA:
BR52039
KEGG:
R11737
|
|
|
|
(E)-phenylacetaldoxime + reduced_flavodoxin + O2 <=> 1-aci-nitro-2-phenylethane + flavin + H2O
|
1.14.14.43
(methylsulfanyl)alkanaldoxime N-monooxygenase
1.14.14.45
aromatic aldoxime N-monooxygenase
|
–
–
|
|
|
BRENDA:
BR52040
KEGG:
R11738
|
|
|
|
(E)-phenylacetaldoxime + L-cysteine + NADPH + O2 + H+ <=> S-(Phenylacetothiohydroximoyl)-L-cysteine + NADP+ + 2 H2O
|
1.14.14.45
aromatic aldoxime N-monooxygenase
|
–
|
K
|
|
KEGG:
R10670
|
|
|
|
(E)-phenylacetaldoxime + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 1-aci-nitro-2-phenylethane + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-11412
|
|
|
|
(E)-phenylacetaldoxime <=> N-benzylformamide
|
not assigned
|
–
|
|
|
MetaCyc:
RXN-12949
|
|
|
|
(E)-phenylacetaldoxime + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (R)-mandelonitrile + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.44
phenylacetaldehyde oxime monooxygenase
|
–
|
|
|
MetaCyc:
RXN-18096
|
|
|
|
(E)-phenylacetaldoxime + O2 + reduced_[NADPH-hemoprotein_reductase] + glutathione <=> S-[(Z)-N-hydroxy(phenyl)acetimidoyl]-L-glutathione + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.45
aromatic aldoxime N-monooxygenase
|
–
|
|
|
MetaCyc:
RXN-18159
|
|
|
|
L-phenylalanine + reduced_[NADPH-hemoprotein_reductase] + O2 <=> (E)-phenylacetaldoxime + oxidized_[NADPH-hemoprotein_reductase] + H2O + CO2
|
1.14.14.40
phenylalanine N-monooxygenase
|
–
|
|
|
MetaCyc:
RXN-4602
|
|
|
|
(E)-phenylacetaldoxime + reduced_flavodoxin + O2 <=> (S)-mandelonitrile + flavin + 2 H2O
|
1.14.14.37
4-hydroxyphenylacetaldehyde oxime monooxygenase
|
–
|
|
|
BRENDA:
BS436644
|
|
|
|
2 O2 + 2 H+ + 2 NADPH + L-phenylalanine <=> CO2 + 3 H2O + 2 NADP+ + (E)-phenylacetaldoxime
|
1.14.14.40
phenylalanine N-monooxygenase
|
–
|
|
|
SABIO-RK:
13084
|
|